MK University distance education syllabus

I want MCA syllabus of MK University of Distance education. Will you provide me?

MK University offered various courses as distance learning mode.

As you want here I am giving syllabus of MK University of Distance education:

MCA Syllabus:
1st year
Mathematical Foundation of Computer Science
Accounting and Financial Management
Programming in C
Digital Principles and Computer Organisation
Communication Skills
Graph Theory
Software Engineering
Relational Database Management Systems
Object oriented programming and C++ language
Micro Processor and Introduction to
Embedded System
Practical:
Programming Lab in C & C++
RDBMS Lab

2nd year
Optimization Techniques
Computer Graphics
System Analysis and Design
Computer Networks
Data Structure Using C++
Computer Based Numerical Methods
Java Programming
Operating Systems
Elective - Neural Networks
Elective - Client Server Technology
Practical:
Graphics & Linux lab
Java lab

3rd year
Web Technology
Principles of Management and Organizational Behavior
Network Programming
Elective - Visual Programming Concepts in Visual C++
Elective - Data Mining & Data Warehousing
Practical:
Web Technology Lab
Visual Programming Lab
Project / Thesis / Viva voce

Contact details:
The Director
Directorate of Distance Education
Madurai Kamaraj University
Palkalai Nagar
Madurai - 625 021,
Tamil Nadu, India
Ph. No.: +91-452-2458471, +91-452-2458265
Email: mkudde@mkudde.org

Map:

I want the syllabus of M.Sc Chemistry of MK University distance education can anybody please provide me this?

As you are looking for the M.Sc Chemistry syllabus of Madurai Kamaraj University distance education so here it is given below

Inorganic Chemistry-I
Organic Chemistry-I
Physical Chemistry-I
Analytical Chemistry-I
Practical – I: Organic Chemistry
Practical – II: Analytical Chemistry

II 1 Inorganic Chemistry-II
Organic Chemistry-II
Physical Chemistry-II
Chemistry of Biomolecules
Practical – I: Inorganic Chemistry
Practical – II: Physical Chemistry


First Year

Paper –I Inorganic Chemistry Unit-1:Covalent and Ionic Bondings
V.B. approach to covalent bonding -Heitler -London, Pauling- Slater refinements,
Hybridization and structure of molecule. VSEPR theory -shapes of molecules. M.O. approach
to covalent bonding -symmetry and overlap of atomic orbitals -symmetry of molecular
orbitals -sigma- pi-and delta -bondings -energy levels in homo -and hetero nuclear diatomic
molecules -bond length, bond order and bond energy -ionic character in a covalent bond. The
concept of multi centre bonding. Structure and bonding in fluorine and oxygen compounds of
xenon and krypton. Bonding in simple tri atomic molecules/ions.
Lattice energy and its calculations by Born-lande and born-Meyer equations -Determinations
by Born –Haber cycle- Kapustinski equation, Energetics of dissolution of ionic compounds in
polar solvents. Properties of ionic compounds- Hardness and electrical conductivity.


Unit II: Chemistry of Lanthanides and Actinides and Studies on Magnetism
Lanthanides- occurrence, extraction and separation techniques (fractional crystalization,
precipitation, ion-exchange, solvent-extraction and thermal decomposition,
selective reduction and oxidation) -position in the periodic table. - electronic configuation -
oxidation states -size relationships -lanthanide contraction -spectral and magnetic properties -
condition compounds of lanthanides -uses of lanthanides and their compounds.
Actinides : Synthesis of elements -position in the periodic table, electronic configuration and
oxidation states- spectral and magnetic properties -comparative account of lanthanides and
actinides.


Magnetism: Types of magnetic behaviour -determination of magnetic susceptibilities by
Gcuy Method and Faraday method -calculation of magnetic moment from experimental data -
magnetic properties of free ions -Effects of ligand field and orbital contribution -magnetic
behaviour of complexes with A, E and T ground terms -Temperature independent
paramagnetism- evaluation of spin orbit coupling constant from spectral and magnetic
moment data -the orbital, contribution reduction factor k-magnetic properties of 3d, 4d, 5d, 4f
and 5f ions anti-ferromagnetic interactions in simple molecules and in lattice structures.


Unit III. Chemistry of Non-aqueous Solvents
Classification of solvents -properties of ionising solvents -a general study of the typical
reactions in liquid ammonia, sulphur dioxide, dinitrogen tetroxide, anhydrous hydrogen
fluoride, sulphuric acid and acetic acid -solution in fused salts non-acqueous titration's.
HSAB concept of acids and bases -acid, base strength and hardness and softness -symbiosis -
theories of hardness and softness -electronegativity and hardness and softness.


Unit IV: Nuclear Chemistry
Properties of nucleus -different types of nuclear forces -liquid drop model, shell model of
nucleus -nuclear reactions induced by charged particles -nuclear reaction cross -section,
significance and determination -theory of nuclear fission -conditions for controlled fission
chain reaction -Nuclear reactor and its components -Production of feed materials for nuclear
reactors -disposal of radioactive wastes- nuclear fusion, steller energy, Application of
radioisotopes in agriculture, industry and medicine -neutron activation analysis -hot atom
chemistry.


Unit V: Chemistry of Solid State
Close packing of atoms and ions FCC,HCP and BCC types of packing tetrahedral and
octahedral void redius ratio -derivation -its influence on structures -representative structures
of AB and AB., types of compounds- rock salt, calcium chloride,wurtzite, sine blende,rutile,
fluorite,antifluorite,cadmimum iodide and nickel arsenide. .Structure of graphite and diamond
-spinels normal and inverse types and perovskite structure.


Diffraction Studies
Crystallographic point groups -space groups -screw, axes and glide planes -Herman -Maugini
notatons seven crystal systems and Bravais lattice Interplanar distance in orthogonal crystal
systems -X-ray diffraction studies -Laue,powder and rotating crystal methods -systematic
absences of refelections and determination oflattice types-data analysis for cubic system.
Electron diffraction by gases: Principle and measurement: determination of structures -
comparison between electron, neutron and X-ray diffractions.
Theories of Metallic bonding Drude-Lorenz theorem and Sommerfield modifications -
MO,VB theories- conductors, insulators and semiconductors -Defects in solid state Schotky
and Frenkel defects-nonstochiometric defects and their consequences.


Paper II : Organic Chemistry - I
Unit I : Electron Displacement, Introduction to Reaction Mechanism and Aromaticity
Electron Displacement : Inductive and field effects - Bond distances - Bond energies-
Delocalised bonds - Cross conjugation - Rules of resonance - The resonance effect - Steric
inhibition of resonance - Hyperconjugation - Hydrogen bonding - Effect of structure on the
dissociation consants of acids and bases.
Introduction to Reaction Mechanisms : Reactive Intermediates - Carbocations, cabanions,
free radicals, carbenes and nitrenes - formation and stability of reactive intermetiates -
Methods of determination of reaction mechanisms - Kinetic and non - kinetic methods -
Kinetic and thermodynamic control of chemical reaction - Priciple of microscopic
reversibility - Hammond postulate - Quantitative treatement of the effect of structure and
reactivity - substituent constants - Limitations and deviations - Taft equation.
Aromaticity : Concept of aromaticiy - Huckels and Criag' rules - Concept of homo - and anti
- aromaticity - cyclopentadienyl anion, fulvene, ferrocene azulene, tropolones, sydnone and
annulenes - Alternant and nonalternant hydrocarbons. NMR and aromaticity.


Unit: II Reaction Mechanisms I - Substitution Reactions
Aliphatic Nucleophilic Substituion : SN1 and SN2 mechanisms - Effect of substrate
structure, attacking nucleophile, leaving group and reaction medium -Ambient nucleophiles
and substrates - Neighbouring group participation -SNi mechanism - Nucleophilic substitution
at allytic, vinylic and aliphatic trigonal carbons-Mechanism of esterification and hydrolysis.
Aliphatic Electrophilic Substitution : Electrophilic substitution at aliphatic saturated carbon
- SE1 SE2 and SEi mechanisms
Aromatic Electrophilic Substitution : Orientation - Reactivity - Mechanisms of Friedel -
Craft reaction, Sulphonation and Gattermann - Koch formylation.
Aromatic Nucleophilic Substitution : SNAr, SN1 mechanisms - Benzyne
mechanism


Unit: III Reaction Mechanism II - Elimation and Addition Reactions
Elimination Reactions : Alpha and beta eliminations - El, E2 and El CB mechanisms -
Sterochemistry of elimination - Orientation of the double bond - Effects of the changes in the
substrate, base, leaving group and reaction medium on El, E2 and E1CB reactions -
Elimination versus substitution - Pyrolytic cis eliminaitons and their stereochemistry Bredt's
rule.


Addition to carbon - carbon multiple bonds : Electrophilic, nucleophilic and free radical
additions - Additions to conjugated systems- Orientation of the addendum -Stereochemical
factors in reactions of addition of hydrogen, HX and HOX -Regioselectivity and
chemoselectivity in additions - Addition of carbenes and carbenoids to double and triple
bonds. Addition to alpha, beta unsaturated carbonyl groups - Michael addition - of Grignard
reagents and lithium dimethyl cuprate - Diels Alder addition.


Addition to carbonyl groups : Mechanisms of Aldol, Benzoin, Claisen and Dieckmann
condensations - Perkin, Knoevenagel, Mannich, Cannizaro, Reformatsky and Darzen's
reactions - Wittig reaction and its modifications.


Unit: IV Stereochemistry and Free Radical Reactions :
Optical Isomerism : Elements of symmetry - Newmann, Sawhorse and Fischer projection
formulae - Concept of Chirality - Cahn Prelog - Ingold system of nomenclature -
Enantiotopic and diastereotopic atoms, groups and faces - Molecules with more than one
chiral center - Molecular dissymmetry due to chiral axes, planes and helicity - Optical
activity of biphenyl, allenes and spiranes, cyclooctene and hexahelicene - Optical activity of
nitrogen and sulphur compounds - Stereospecific and Stereoselective synthesis - Resolution,
recemisation and asymmetric synthesis - Crams' and prelog's rules.
Geometrical Isomerism : E, Z nomenclature - Determination of configuration of geometrical
isomers - stereomutation - Stereoisomerism in monocyclic compounds (upto six - membered
rings)


Free Radical Reactions : Formation, detection and stability of free radicals - Free radical
reactions - Halogenation, addition, oxidation, reduction and rearrangement reactions - Barton,
Sandmeyer, Gomberg - Bachmann, Ullmann, Pschorr and Hunsdiecker reactions.


Unit: V Heterocyclic compounds
Structure, synthesis and reactions of indole, carbozole, oxazole, imidazole and thiazole
Pyrimidines - Generai chemistry and detailed study of uracil, thymine and cytosine.
Purines - General chemistry and detailed study of uric acid and caffeine.
Flavones - General chemistry and detailed study of quercetin. Isoflavones - General
chemistry and detailed study of genistein. Anthocyanins - General chemistry and detailed
study of cyanidin chloride
Coumarins - General chemistry and detailed study of umbelliferone.


PAPER–III
PHYSICAL CHEMISTRY -1
Unit I : Thermodynamics
Second law of thermodynamics – Entropy – Entropy changes of an ideal gas – Entropy in
changes of state – Entropy of mixing – Free energy and its temperature dependence –
Equilibrium constant Gibbs free energy – Maxwell relations and thermodynamics equations
of state. Third law of thermodynamics – Third law entropies – Partial molar quantities –
Partial molar volume – chemical potential – Gibbs – Duhem equation – Fugacity and activity
– Elements of non-equilibrium thermodynamics.


Unit II : Electrochemistry
Ion activity and activity coefficient – Ionic strength – Debye – Huckel theory – Limiting Law
– Ionic association – Molar conductivity – Debye – Huckel – Onsager equation –
Applications of conductivity measurement – Electrode potential. Standard electrode
(reduction) potentials – Nernst equation. Potential diagrams – free energy contribution to
electrode potentials. Types of electrodes and electrochemical cells – Applications of cell
EMF values G, S and H calculations. Calculation of equilibrium constants and solubility
products – Over voltage – Butler – Volmer equation, Tafel equation – Fuel cells – Corrosion.


Unit III : Chemical Kinetics and Catalysis
Theory of reaction rates – Collision theory – Absolute reaction rate theory –Theory of
unimolecular reactions – Chain reactions – Explosive reactions – Kinetic salt effect – Kinetic
isotope effect – Fast reactions – Chemical relaxation – Reactions in flow sysems – Chemical
Kinetics in crossed molecular beam – molecular dynamics – Temperature dependence of
reaction rates – Homogeneous catalysis – acid – base catalysis – acidity functions – Enzyme
catalysis.
Unit IV : Quantum Theory–I
Black body radiation – Photoelectric effect – de Broglie relation and Heisenberg's uncertainty
principle – Postulates of quantum theory – Operator algebra – Schrodinger equation. Eigen
functions and eigen values for particle in a ID and a 3D box, rigid rotor and simple harmonic
oscillator – tunnel effect.
Unit V : Quantum Theory–II
Angular momentum – Hydrogen atom problem – radial distribution functions. Need for
approximation methods. Variation and perturbation methods – Applications to hydrogen and
helium atoms – SCF method – HMO calculations for allyl system butadiene, and benzene.

Analytical Chemistry


Unit- I: Applications of UV, IR and NMR Spectrosopic Techniques
UV- Visible spectroscopy: Basic principle - Process of electronic excitation n-_ and _-_
transitions - Transition probability - Solvent effect -Factors affecting position and intensity
ofabsorption bands -Spectra of dienes, polyenes and unsaturated ketones -Woodward -Fiesher
rules.


I R Spectroscopy: Stretching vibrations -Hooke's Law -Stretching and ending vibrations -
force constants -Fundamentals, overtone and combination bands -Fermi resonance -
Applications of 1R spectroscopy -Identity of samples -Characteristic group frequency -
Effects of substitution, conjugation, bond angle distortion of geometry and hydrogen bonding
on vibrational frequencies-detecting inter-and intra-molecular hydrogen bondings.
Frequencies of absorption for sulphate, nitrate, chlorate ions and ammonia and water
molecule-shift in frequencies upon coordination.


Infrared instrumentation and techniques. Source of ir-radiations, monochromatization,
cell and prim materials, measuring intensities of ir radiations. Sample handling techniques


NMR spectroscopy: HNMR -Introduction, to principles -instrumentation -Chemical shift,
spin-spin coupling - peak area -homotopic, enantiotopic and diastcreotopic relationships -first
order and non first order spectra factors - aftecting spin-spin splitting-width of lines-
Dueterium substitution and shift reagents- double reasonance technique. Basic concepts of FT
-MMR13 CNMR. Comparison of Hand and CNMR -Fourier transformation -Chemical shift
and its dependence -C-C & C-H couplings -Off resonance and broad band decouplings -
Application in structural elucidation, application ofl9F 31T,10,11 B resonance studies to
inorganic systems and organometailics- fluctional behaviour.


Unit II :Mass Spectrometry, ORD and CD and Chromatographic Methods

Mass spectometry: Principle- Parent ion, metastable ion& isotopic ions -Base peak -Genera!
rules of fragmentation -MacLafferty rearrangement -Retro Diels-Alder reaction.
ORD & CD : Principle- Circular birefringence and circular dichroism -Cotton effect -Types
of ORD curves-Applications of plain dispersion curves -Application of Cotton effect curves -
Alpha halo ketone and Octant rules-Applications for determination of conformation and
configuration.


Chromatographic methods: Definition and classification of chromatographic techniques -
Elementary treatment of the principle & practice of adsorption, partition, paper, thin-layer,
HPLC and gas chromatographic techniques.


Unit III : Electrochemical analysis
Reference electrodes -indicator electrodes - ion-exchange membrance and solid state
electrodes -their construction and working Direct potentiometry -potentiometric titration'sacid-
base, redox, precipitation and complexometric titrations by potentiometry. Theory of
electrolysis-concentration and kinetic over potentials -estimate of applied voltage for
electrolysis -depolarisers -electrogravimetry -constant potential and constant current
electrolysis. Coulometry and coulometric titrations polarography- dropping mercury and
rotating mercury electrodes -polarograms half-wave potential- diffusion current and Ilkovic
equation -amperometry -cyclic voltammetry.


Unit - IV: Error Analysis and Computer Programming
Significant figures and their importance in calculations -precision and accuracy -determinate
and indeterminate errors-measures of precision -statistical concepts -standard or normal error
curve and its features -reliability of mean values -confidence limits -distribution and
confidence levels -Regression -distribution of data of a liner curve-method of propagation of
errors -Rejection of observation 2. 5a, 4a and Q tests.


Basic Programming: Constants, variables- expressions -hierarchy of operations -arithmetic
statements -I/O state-Statements -Branching -conditional branching - loops -library functions.
.
Subscripted variables and subroutines-DIM statements - Array - one-dimensional and twodimensional-
matrix manipulations -DEF function -GOSUB and Return statements -Graphics
LINE, CIRCLE, PSET statements-Simple programs for Chemistry.
MS EXCELL PACKAGE: (Version Excel 2000) components of spread sheets -Books-sheetspages-
naming files -formatting cell and rows. Editing data in a cell-copying- pasting -
constructing cell and rows. Editing data in a cell-copying- pasting -constructing formula in
cells -absolute and - relative referencing of cell and inter transfer of data inserting Charts -
constructing spread sheets for calculation in chemistry by invoking functions in cells -least
square, Curve fitting -polynomials and evaluating coefficients invoking Excel Solver -
statistical calculations -developing spread sheets for potentiometric titration -data processing
-pKa values of weak acids from pH volume data employing Henderson equation. (Text book:
Ira N Levine, 'Physical Chemistry', Tata Mcgraw Hill, New Delhi, Edn. V, 2002 and Rick
Winter & Patry N. Winter, "Using Microsoft Office & Professional (que series), special
edition, Printice Hall of India Pvt.Ltd., New Delhi, 5th Edn., 1998 or later Version ).


UNIT V : Thermal and spectrophotometric methods of analysis and environmental
chemistry.
Principles of TGA, DTA and DSC -application to simple salts -oxy salts, carbonates and
complex salts. Thermometric titrations.
Laws of absorption and quantitative law of luminescence -principles and applications of
photometry, fluorimetry, turbidimetry and nepheometry -photometric titrations -
multicomponent analysis -tlame spectrophotometry -absorption and emission photometry.


Environmental Chemistry :
Water pollution -dissolved oxygen -BOD, COD -heavy metals as pollutants -thermal
pollution -chemical pollution -role of fertilizers and detergent builders and pesticides -
industrial wastes and purification of water by classical and modern methods. Air pollution -
sources -pollutions SO2, NO, CO, hydrocarbons and industrial and photochemical smog.
Pollution of upper atmosphere -greenhouse effect. Chemical at toxicology -biochemical
effect of heavy metals -PAN and cyanide. Use of IR in environmental pollution studies.


here i am giving link of MK University distance education M.Sc Chemistry syllabus

mkudde.org/download/syllabus/MSc_chemistry.pdf

Contact Details:
Madurai Kamaraj University
Alagar Kovil Main Road, Madurai, Tamil Nadu ‎
0452 245 8471 ‎

Map location:

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