IIT JEE question papers

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IIT JEE Main Exam Solution 2013
An unknown alcohol is treated with the Lucas reagent to determine whether the alcohol is primary,
secondary or tertiary. Which alcohol reacts fastest and by what mechanism:
(1) tertiary alcohol by SN1 (2) secondary alcohol by SN2
(3) tertiary alcohol by SN2 (4) secondary alcohol by SN1
Sol. (1)

The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCl with 250 mL of 2(M)HCl will be:
(1) 1.00 M (2) 1. 75 M
(3) 0.975 M (4) 0.875 M
Sol. (4)

5. Which of the following is the wrong statement?
(1) O3 molecule is bent (2) Ozone is violet-black in solid state
(3) Ozone is diamagnetic gas (4) ONCl and ONO–are not isoelectronic
Sol. (All the options are correct statements)





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Here you need IIT JEE Solutions Question Papers

The question paper consists of 3 parts

(Physics, Chemistry and Mathematics)

Each part consists of three sections.

Section I
Contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which Only One is correct.

Section II
contains 3 paragraphs each describing theory, experiment, data etc. There are 6 multiple choice questions relating to three paragraphs with
2 questions on each paragraph. Each question of a particular paragraph has four choices (A), (B), (C) and (D) out of which only one is correct.

Section III
Contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which one or more are correct.

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An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary,

secondary or tertiary. Which alcohol reacts fastest and by what mechanism:

(1) tertiary alcohol by SN1 (2) secondary alcohol by SN2

(3) tertiary alcohol by SN2 (4) secondary alcohol by SN1

The first ionization potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be:

(1) – 5.1 eV (3) –10.2 eV

(3) + 2.55 eV (4) – 2.55 eV

The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCl with 250 mL of 2(M)HCl will be:

(1) 1.00 M

(2) 1. 75 M

(3) 0.975 M (4) 0.875 M

Which of the following is the wrong statement?

(1) O3 molecule is bent (2) Ozone is violet-black in solid state

(3) Ozone is diamagnetic gas (4) ONCl and ONO–

are not isoelectronic

Four successive members of the first row transition elements are listed below with atomic numbers. Which

one of them is expected to have the highest 3 2

0

M /M

E + + value?

(1) Mn(Z = 25) (2) Fe(Z = 26)

(3) Co(Z = 27) (4) Cr(Z = 24)

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