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Old January 29th, 2014, 12:10 PM
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Default 12th Chemistry Compartment Exam Important topics

I got compartment in chemistry subject and now preparing for compartment exam. Can you please suggests some topics?

As you have got compartment in chemistry subject, then it would be beneficial for you to cover few topics of more weightage rather then covering the whole syllabus, because it would be the total wastage of time. At present for you the priority is to get passing marks. Below the list of few important topics are given.
Electrochemistry
Solid States
Chemical Kinetics
Surface Chemistry
P-block elements
D and F block elements.

1. Some basic concepts in Chemistry
Importance of Chemistry, physical quantities and their measurement in Chemistry, SI Units, uncertainty in measurements and use of significant figures, Unit and dimensional analysis, Matter and its nature, laws of chemical combinations, atomic, and molecular, masses mole concept, molar masses, percentage composition and molecular formula, chemical stoichiometry.
2. States of matter
Three states of matter, gaseous state, gas laws (Boyle's Law and Charles Law), Avogadro's Law, Grahams'Law of diffusion, Dalton's law of partial pressure, ideal gas equation, Kinetic theory of gases, real gases and deviation from ideal behaviour, van der Waals’ equation, liquefaction of gases and critical points, Intermolecular forces; liquids and solids.
3. Atomic structure
Earlier atomic models (Thomson's and Rutherford) , emission spectrum of hydrogen atom, Bohr's model, of hydrogen atom, Limitations of Bohr’s model, dual nature of matter and radiation, Heisenberg uncertainty principle, quantum mechanical model of atom (quantum designation of atomic orbitals and electron energy in terms of principal, angular momentum and magnetic quantum numbers), electronic spin and spin quantum numbers, Pauli’s exclusion principle, general idea of screening (constants) of outer electrons by inner electrons in an atom, Aufbau principle, Hund's rule, atomic orbitals and their pictorial representation, electronic configurations of elements.
4. Classification of elements and periodicity in properties
Need and genesis of classification of elements (from Doebereiner to Mendeleev), Modern periodic law and present form of periodic table, Nomenclature of elements with atomic number > 100, electronic configurations of elements and periodic table, electronic configuration and types of elements and s, p, d and f blocks, periodic trends in properties of elements (atomic size, ionization enthalpy, electron gain enthalpy, valence/ oxidation states and chemical reactivity).
5. Chemical energetics
Some basic concepts in thermodynamics, first law of thermodynamics, heat capacity, measurement of Uand H, calorimetry, standard enthalpy changes, thermochemical equations, enthalpy changes during phase transformations, Hess's Law, standard enthalpies of formation, bond enthalpies and calculations based on them.
6. Chemical bonding
Kossel -Lewis approach to chemical bond formation, ionic bonds, covalent bonds, polarity of bonds and concept of electronegativity, valence shell electron pair repulsion (VSEPR) theory , shapes of simple molecules, valence bond theory, hybridization involving s, p and d orbitals and shapes of molecules  and  bonds; Molecular orbital theory involving homounclear diatomic molecules; Hydrogen-bonding.
7. Equilibrium
Equilibrium in physical and chemical processes
Equilibrium in physical and chemical processes, dynamic equilibrium, law of chemical equilibrium and equilibrium constant, homogeneous equilibrium, heterogenous equilibrium, application of equilibrium constants, Relationship between reaction quotient Q, equilibrium constant, K and Gibbs’ energy G; factors affecting equilibrium-Le Chateliar's principle.
Ionic equilibrium
Acids, Bases and Salts and their ionization, weak and strong electrolytes degree of ionization and ionization constants, concept of pH, ionic product of water, buffer solution, common ion effect, solubility of sparingly soluble salts and solubility products.
8. Redox reactions
Electronic concepts of reduction - oxidation, redox reactions, oxidation number, balancing of redox reactions.
9. Solid state Chemistry
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids; unit cells in two dimensional and three dimensional lattices, calculation of density of a unit cell, packing in solids, voids, number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties.
10. Chemical thermodynamics
Spontaneous processes, energy and spontaneity , entropy and second law of thermodynamics, concept of absolute entropy, Gibbs energy and spontaneity, Gibbs energy change and equilibrium constant.


11. Solutions
Types of solutions, different units for expressing concentration of solution, mole fraction, percentage (by volume and mass both), definitions of dilute solutions, vapour pressure of solutions and Raoult's Law, Colligative properties, lowering of vapour pressure, depression of freezing point, elevation of boiling points and osmotic pressure, determination of molecular masses using colligative properties, abnormal values of molecular masses, van’t Hoff factor. simple numerical problems.
12. Chemical kinetics
Rate of chemical reactions, factors, affecting rates of reactions –concentration, temperature and catalyst, order and molecularity of reactions, rate law and rate constant, differential and integral forms of first order reaction, half-life (only zero and first order) characteristics of first order reaction, effect of temperature on reactions, Arrhenius theory - activation energy, collision theory of reaction rate (no derivation).
13. Electrochemistry
Conductance in electrolytic solutions, specific and molar conductivity, variation of conductivity with concentration, Kohlrausch's law, electrolysis and laws of electrolysis (elementary idea), electrolytic and galvanic cells, emf. of a cell, standard electrode potential, Nernst equation, concentration cell, fuel cells, cell potential and Gibbs energy, dry cell and lead accumulator.
14. Surface chemistry
Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on solids, catalysis, homogeneous and heterogeneous activity and selectivity, enzyme catalysis, colloidal state, distinction between true solutions, colloids and suspensions; lyophillic, lyophobic, multimolecular and macromolecular colloids, properties of colloids, Tyndal effect, Brownian movement, electrophoresis, coagulation, emulsions - type of emulsions.
15. Hydrogen
Position of hydrogen in periodic table, isotopes of hydrogen, heavy water, hydrogen peroxide-preparation, reactions and structures; hydrides and their classification.
16. s-Block Elements (Alkali and Alkaline Earth metals):
Group 1 and Group 2 elements
Electronic configurations and general trends in physical and chemical properties, anomalous properties of the first element of each group, diagonal relationship.
Preparation and properties of some important compounds, sodium carbonate, sodium hydroxide, sodium hydrogen carbonate and industrial uses of lime and limestone, biological significance of Na, K, Mg and Ca.
17. General principles and processes of isolation of elements
Principles and methods of extraction - concentration, reduction, (chemical and electrolytic methods), and refining.
Occurrence and principles of extraction of Al, Cu, Zn and Fe.
1 8. p-Block Elements
Introduction to p-block elements
Electronic configurations and general trends in properties, viz. atomic sizes, ionization enthalpies, electronegativity values, electron gain enthalpies and oxidation states across the periods and down the groups in the p-block.
Unique behaviour of the top element in each group of the block - the covalency limit and the p - p overlap in some molecules (e.g. N2, O2) and its consequences; general trend in catenation tendency down each group.
Group-wise study of the p-block Elements
Group 13 - In addition to the general characteristics as outlined above, properties and uses of aluminium, nature of hydrides/ halides and oxides; Properties, structures and uses of diborane boron halides, aluminium chloride, borax, boric acid and alums.
Group 14 - In addition to the general characteristics; carbon – catenation, allotropic forms (diamond and graphite), properties and structures of oxides; silicon - silicon tetrachloride, and structures and uses of silicates, silicones and zeolites.
Group 15 - In addition to the general characteristics, the general trends in the nature and structures of hydrides, halides and oxides of these elements. Preparation and properties of ammonia, nitric acid, phosphine and halides of phosphorus, structures of the oxoacids of phosphorus.
Group 16 - In addition to the general characteristics, preparations, properties and uses of dioxygen, simple oxides, ozone; sulphur - allotropic forms, compounds of sulphur, preparation, properties and uses of sulphur dioxide and sulphuric acid, industrial preparations of sulphuric acid, structures of oxoacids of sulphur.
Group 17 - In addition to the general characteristics, occurrence, trends in physical and chemical properties, oxides and oxoacids of halogens (structures only), preparation, properties and uses of chlorine and hydrochloric acid, trends in the acidic nature of hydrogen halides. Interhalogen compounds (structures only).
Group 18 - General introduction, electronic configurations, occurrence, trends in physical and chemical properties and uses, - fluorides and oxides of xenon (structures only).
19. The d-and f-Block elements
General introduction, electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals –physical properties, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic property, interstitial compounds, alloy formation; preparations and properties of K2Cr2O7 and KMnO4.
Lanthanoids - Electronic configuration and oxidation states, chemical reactivity and lanthanoid contraction.
Actinoids - Electronic configuration and oxidation states.
20. Coordination compounds
Introduction to ligands, coordination number, colour, magnetic properties, and shapes; IUPAC - nomenclature of mononuclear coordination compounds, isomerism , bonding-valence bond approach to the bonding and basic ideas of Crystal Field Theory, colour and magnetic properties. Elementary ideas of metal - carbon bonds and organometallic compounds, importance of co-ordination compounds (in qualitative analysis, extraction of metals and biological systems).
21. Some basic principles of Organic Chemistry
- Tetravalence of carbon, hybridization ( s and p ), shapes of simple molecules, functional groups:-C=C-, -C C- and those containing halogens, oxygen, nitrogen and sulphur; homologous series, isomerism.
- General introduction to naming organic compounds-trivial names and IUPAC nomenclature.
- Electronic displacement in a covalent bond; inductive effect, electromeric effect, resonance and hyperconjugation. Fission of covalent bond: free radicals, electrophiles and nucleophiles, carbocations and carbonanions.
- Common types of organic reactions: substitution, addition, elimination and rearrangement reactions.
22. Hydrocarbons
Alkanes and cycloalkanes : classification of hydrocarbons, alkanes and cycloalkanes, nomenclature and conformations of alkanes and cycloalkanes.
Alkenes and alkynes : Nomenclature and isomerism, general methods of preparation, properties (physical and chemical), mechanism of electrophilic addition, Markownikoff’s rule, peroxide effect, acidic character of alkynes, polymerisation reactions.
Aromatic hydrocarbons: Benzene and its homologues, nomenclature, sources of aromatic hydrocarbons (coal and petroleum), structure of benzene, chemical reaction of benzene-mechanism of electrophilic substitution. Directive influence of substituents and their effect on reactivity.
Petroleum and petrochemicals : Composition of crude oil fractionation and uses, quality of gasoline, LPG, CNG, cracking and reforming, petrochemicals.
23. Purification and characterization of carbon compounds
- Purification of carbon compounds : filtration, crystallisation, sublimation, distillation chromatography,
- Qualitative analysis : detection of nitrogen, sulphur, phosphorus and halogens.
- Quantitative analysis : estimation of different elements (H, N, halogens, S and P)
- Determination of molecular masses : Silver salt method, chloroplatinate salt method, calculations of empirical and molecular formulas.
24. Organic compounds with functional groups containing halogens (X)
- Nature of C-X bond in haloalkanes and haloarenes, nomenclature, physical and chemical properties, mechanism of substitution reactions, reactivity of C-X bond in haloalkanes and haloarenes.
- Some commercially important compounds : dichloro, trichloro and tetrachloromethanes; p-dichlorobenzene, freons, BHC, DDT, their uses and important reactions.
25. Organic compounds with functional groups containing oxygen
Alcohols and phenols : Nomenclature, methods of preparation, physical and chemical properties; chemical reactivity of phenols in electrophilic substitutions, acidic nature of phenol, ethers: electronic structure, structure of functional group, nomenclature, important methods of preparation, physical and chemical properties, some commercially important compounds.
Aldehydes and ketones : Electronic structure of carbonyl group, nomenclature, important methods of preparation, physical properties and chemical reactions, relative reactivity of aldehydic and ketonic groups, acidity of -hydrogen, aldol condensation. Connizzarro reaction, nucleophilic addition reaction to >C=O groups.
Carboxylic acids : Electronic structure of-COOH, Nomenclature, important methods of preparation, physical properties and effect of substituents on -carbon on acid strength, chemical reactions.
Derivatives of carboxylic acids : Electronic structure of acid chloride, acid anhydride, ester and amide groups, nomenclature, important methods of preparation, comparative reactivity of acid derivatives. Some commercially important compounds.
26. Organic Compounds with functional group containing nitrogen
- Structure, nomenclature of nitro, amino, cyano and diazo compounds.
- Nitro compounds – important methods of preparation, physical properties and chemical reactions.
- Amines : primary, secondary and tertiary amines, a general awareness, important methods of preparation, physical properties, basic character of amines, chemical reactions.
- Cyanides and isocyanides : preparation, physical properties and chemical reactions.
- Diazonium salts : Preparation, chemical reaction and uses of benzene diazonium chloride. Some commercially important nitrogen containg carbon compounds, (aniline, TNT)
27. Polymers
Classification of polymers, general methods of polymerization-addition and condensation: addition-free radical, cationic, anionic polymerization, copolymerisation, natural rubber, vulcanization of rubber, synthetic rubbers, condensation polymers, idea of macromolecules, biodegradable polymers.
Some commercially important polymers (PVC, teflon, polystyrene, nylon-6 and 66, terylene and bakelite).
28. Environmental Chemistry
Environmental pollution – air, water and soil pollutions, chemical reactions in atmosphere, smogs, major atmospheric pollutants, acid-rain, ozone and its reactions, effects of depletion of ozone layer, green house effect and global warming – pollution due to industrial wastes, green chemistry as an alternative tool for reducing pollution, strategy for controlling environmental pollution.
29. Biomolecules
Carbohydrates : Classification, aldose and ketose, monosaccharides (glucose and fructose), oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen); important simple chemical reactions of glucose, elementary idea of structure of pentose and hexose.
Proteins : Elementary idea of -amino acids, peptide bond, polypeptides, proteins; primary, secondary and tertiary structure of proteins and quaternary structure (gualitative idea only), denaturation of proteins, enzymes.
Vitamins : Classification and functions
Nucleic acids : Chemical composition of DNA and RNA
Lipids : Classification and structure
Hormones : Classification and functions in biosystem.
30. Chemistry in everyday life
- Chemicals in medicines – analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antacids, antihistamins.
- Chemicals in food – preservativess, artificial sweetening agents.
- Cleansing agents – soaps and detergents, cleansing action.
- Rocket propellants : characteristics and chemicals used.

As you want to get CBSE 12th chemistry Exam Important topics so here I am giving you some topics:

Solid State
Solutions
Electrochemistry
Chemical Kinetics
Surface Chemistry
Isolation of Elements
p-Block Elements
d- and f-Block Elements
Coordination Compounds
Haloalkanes and Haloarenes
Alcohols, Phenols and Ethers
Aldehydes, Ketones and Carboxylic Acids
Organic Compounds containing Nitrogen
Biomolecules
Polymers
Chemistry in Everyday Life

Syllabus:

Unit I: Solid State
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and three dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids, number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties. Band theory of metals, conductors, semiconductors and insulators and n & p type semiconductors.

Unit II: Solutions
Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, colligative properties - relative lowering of vapour pressure, Raoult's law, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties, abnormal molecular mass, van't Hoff factor.

Unit III: Electrochemistry
Redox reactions, conductance in electrolytic solutions, specific and molar conductivity, variations of conductivity with concentration, Kohlrausch's Law, electrolysis and law of electrolysis (elementary idea), dry cell -electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells, Relation between Gibbs energy change and emf of a cell, fuel cells, corrosion.

Unit IV: Chemical Kinetics
Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration, temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant, integrated rate equations and half life (only for zero and first order reactions), concept of collision theory (elementary idea, no mathematical treatment). Activation energy, Arrhenious equation.

Unit V: Surface Chemistry
Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on solids, catalysis, homogenous and heterogenous activity and selectivity; enzyme catalysis colloidal state distinction between true solutions, colloids and suspension; lyophilic , lyophobic multimolecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement, electrophoresis, coagulation, emulsion - types of emulsions.

Unit VI: General Principles and Processes of Isolation of Elements
Principles and methods of extraction - concentration, oxidation, reduction - electrolytic method and refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.

Unit VII: p - Block Elements
Group 15 Elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; nitrogen preparation properties & uses ; compounds of nitrogen, preparation and properties of ammonia and nitric acid, oxides of nitrogen (Structure only) ; Phosphorus - allotropic forms, compounds of phosphorus: preparation and properties of phosphine, halides PCl3 , PCl5 and oxoacids (elementary idea only).
Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties,dioxygen: Preparation, Properties and uses, classification of oxides, Ozone, Sulphure -allotropic forms; compounds of sulphure: Preparation properties and uses of sulphur-dioxide, sulphuric acid: industrial process of manufacture, properties and uses; oxoacids of sulphur (Structures only).
Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens, Preparation properties and uses of chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens (structures only).
Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.

Unit VIII: d and f Block Elements
General introduction, electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals - metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation, preparation and properties of K2Cr2O7 and KMnO4.
Lanthanoids - Electronic configuration, oxidation states, chemical reactvity and lanthanoid contraction and its consequences.
Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids.

Unit IX: Coordination Compounds
Coordination compounds - Introduction, ligands, coordination number, colour, magnetic properties and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner's theory, VBT, and CFT; structure and stereo isomerism, importance of coordination compounds (in qualitative inclusion, extraction of metals and biological system).

Unit X : Haloalkanes and Haloarenes
Haloalkanes: Nomenclature, nature of C-X bond, physical and chemical properties, mechanism of substitution reactions, optical rotation.
Haloarenes: Nature of C -X bond, substitution reactions (Directive influence of halogen in monosubstituted compounds only. Uses and environmental effects of - dichloromethane, trichloromethane, tetrachloromethane, iodoform freons, DDT.

Unit XI: Alcohols, Phenols and Ethers
Alcohols: Nomenclature, methods of preparation, physical and chemical properties( of primary alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration, uses with special reference to methanol and ethanol.
Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols.
Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.

Unit XII: Aldehydes, Ketones and Carboxylic Acids
Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties, mechanism of nucleophillic addition, reactivity of alpha hydrogen in aldehydes: uses.
Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.

Unit XIII: Organic compounds containing Nitrogen
Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary, secondary and tertiary amines.
Cyanides and Isocyanides - will be mentioned at relevant places in context.
Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.

Unit XIV: Biomolecules
Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L configuration oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen) importance.
Proteins - Elementary idea of α - amino acids, peptide bond, polypeptides, proteins, structure of proteins - primary, secondary, tertiary structure and quaternary structures (qualitative idea only), denaturation of proteins; enzymes. Hormones - Elementary idea excluding structure. Vitamins - Classification and functions.
Nucleic Acids: DNA and RNA.

Unit XV: Polymers
Classification - natural and synthetic, methods of polymerization (addition and condensation), copolymerization, some important polymers: natural and synthetic like polythene, nylon polyesters, bakelite, rubber. Biodegradable and non-biodegradable polymers.
Unit XVI: Chemistry in Everyday life

Chemicals in medicines - analgesics, tranquilizers antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines.
Chemicals in food - preservations, artificial sweetening agents, elementary idea of antioxidants.
Cleansing agents - soaps and detergents, cleansing action.

Last edited by Aakashd; December 24th, 2019 at 02:32 PM.
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  #2  
Old August 8th, 2015, 08:11 PM
kshitij soni
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Exclamation chemistry problems

can i Plz have some important topics of chemistry compartment......bcoz i dnt knw hw to prepare now actully i lost my confidence bcoz of that compartment....so plz help me .......plz
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