Rajasthan Univ M.Sc Chemistry Question paper

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01. What is nephlauxetic effect?


02. Give one evidence for metal ligand orbital overlap.

03. Explain Irwing William order of stability of complexes.

04. Account for the difference in intensities of colours of aqueous solutions
of Na2CrO4 and

Cr(NO3)3. Give the origin of those colours.

05. How CD spectra is useful in determining the absolute configuration of
metal complexes?

06. Derive the ground term symbol for octahedral Cr3+ ion.

07. Explain the d orbital splitting diagrams of for triagonal-bipyramidal and
square

pyramidal complexes of formula ML5. What would be the expected magnetic
properties

of such complexes of Ni(II)?

09. What is trans effect? What would be the sequence of substitutions
required to get

[PtClBrNH3Py] ( with Br trans to Cl) from [Pt Cl4]2-?

10. Explain Curies law? What is its significance?

11. How many d-d bands would be expected in the electronic spectrum of an
octahedral

Cr(III) complex?

12. Explain the difference between 4f and 5f orbitals.

13. Electronic absorption spectra of lanthanide ions are very sharp. Explain.

14. How can Ni(II) complexes with various geometries be distinguished
using their electronic

spectra?

15. What is Jahn-Teller effect? How electronic spectra could be used to
detect Jahn-Teller

distortion in transition metal complexes?

16. What are the merits and demerits of crystal field theory of complexes?

17. Distinguish between Orgel diagrams and Tanabe-Sugano diagrams.

18. Explain Temperature Independent Paramagnetism with suitable
examples.

19. What is meant by circular dichroism and ORD? Discuss the important
applications of

Cotton effect in coordination chemistry.

20. What is meant by stability of a complex? Explain the factors determining
the stability of

a complexes.

21. Explain the use of lanthanide complexes as shift reagents.