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Is the type of questions in VITMEE same as Gate? How much marks will be needed to qualify VITMEE for Electrical engineering branch? Ok, as you are preparing for VITMEE exam so here I am providing you the syllabus of Chemistry. VITMEE Chemistry Syllabus Atomic Structure Planck’s quantum theory – wave particle duality -Heisenberg’s principle – Schrodinger equation – particle in a box and hydrogen atom – VB and MO theories. Spectroscopy Rotational and vibrational spectra – harmonic unharmonic oscillator and Rigid Rotor – selection rules – fundamentals, overtones and combinational bands – calculation of force constants (diatomic molecules) – Group requencies – electronic spectroscopy – potential energy diagram – term symbols – selection rules – LS and JJ coupling – Frank Condon principle – oscillator’s strength – effect of solvent’s on spectrum. Thermodynamics First law of thermodynamics – second law – third law terms and their relations. Chemical kinetics and equilibrium Rate constants of chemical reactions, temperature dependence, collision and transition state theories -consecutive and parallel reactions – chemical equilibrium and response of chemical equilibrium to temperature and pressure. d and f block elements General characteristics of d and f block elements; coordination chemistry structure and isomerism, stability, theories of metal-ligand bonding (CFT and LFT), mechanisms of substitution and electron transfer reactions of coordination complexes. Electronic spectra and magnetic properties of transition metal complexes, lanthanides and actinides. Metal carbonyls, metal-metal bonds and metal atom clusters, metallocenes; transition metal complexes with bonds to hydrogen, alkyls, alkenes and arenes; metal carbenes; use of organometallic compounds as catalysts in organic synthesis. Bioinorganic chemistry of Na, K, Mg, Ca, Fe, Co, Zn, Cu andMo. SolidState Crystal systems and lattices, Miller planes, crystal packing, crystal defects; Bragg’s Law, ionic crystals, band theory, metals and semiconductors, different structures of AX, AX2, AX3 compounds, spinlals. Instrumental methods of analysis Atomic absorption and emission spectroscopy including ICP-AES, UV-visible spectrophotometry, NMR, Mass, Mossbauer spectroscopy (Fe and Sn), ESR spectroscopy, chromatography including GC and HPLC and electro-analytical methods (coulometry, cyclic voltammetry, polarography – amperometry, and ion selective electrodes). Determination of structures of organic and inorganic compounds using UV-visible, IR, NMR and mass spectroscopy. Stereochemistry Chirality of organic molecules with or without chiral centres. Specification of configuration in compounds having one or more stereogenic centres. Enantiotopic and diastereotopic atoms, groups and faces. Stereospecific synthesis. Conformational analysis of acyclic and cyclic compounds. Geometrical isomerism. Configurational and conformational effects on reactivity and selectivity/ specificity. Reaction Mechanism Electrophilic and Nucleophilic substitution informations in aliphatic and aromatic compounds various mechanisms Addition and Elimination reactionsvarious mechanisms Reaction intermediates carbocations, carbanions, carbenes, nitrenes and free radicals. Organic synthesis Synthesis, reactions, mechanisms and selectivity involving the following – alkenes, alkynes, arenes, alcohols, phenols, aldehydes, ketones, carboxylic acids and their derivatives, halides, nitro compounds and amines. Use of compounds of Mg, Li, Cu, B and Si in organic synthesis. Concepts in multistep synthesis – retrosynthetic analysis, disconnections, synthons, synthetic equivalents, reactivity umpolung, selectivity, protection and deprotection of functional groups. Heterocyclic compounds Structure and reactions of furan, pyrrole, thiophene, pyridine, indole and their derivatives. Biomolecules Structure, properties and reactions of mono- and di-saccharides, physicochemical properties of amino acids, chemical synthesis of peptides, structural features of proteins, nucleic acids, steroids, terpenoids, carotenoids, and alkaloids. Last edited by Gunjan; July 3rd, 2019 at 12:05 PM. |