Syllabus Of Msc Chemistry In Kanpur University

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Kanpur University Msc Chemistry Syllabus

Paper -I Inorganic Chemistry 120

Paper -II Organic Chemistry 120

Paper -III Physical Chemistry 120

Paper -IV Group Theory and Spectroscopy 100

Paper -V (11) Mathematics for Chemists

(for Biology Students)
OR . 30
Biology for Chemists
(for Mathematics Students)
(1)) Computers for Chemists 60
_ Total Theory 550
Practical 200

Candidates will be required to pass in Theory and Practical separately.

Paper ' I
Inorganic Chemistry
I Stercochemistry and Bonding in Main Group
Compounds
VSEPR, Walsh diagrams (tri- and penta- atomic
molecules), (11! — pIt bonds, Bent rule and energetics of
hybridization, some simple reactions of covalently bonded
molecules

Metal-Ligand Equilibria in Solution
Stepwise and overall formation constants and their
interaction. trends in stepwise constants, factors affecting
the stability of metal complexes with I’Efl-BTEUCB to the
nature of metal ion and ligand, chelate reflect and its
thermodynamic origin, determination of binary formation
constants by pH-metry and spectrophotometry.
Reaction Mechanism of Transition Metal complexes
Energy profile of a reaction, reactivity of metal complexes,
inert and labile complexes, kinetic application of valence
bond and crystal field theories, kinetics of octahedral
substitution. acid hydrolysis, factors affection, acid
hydrolysis, base hydrolysis, conjugate base mechanism,
direct and indirect evidences in favour of conjugate
mechanism, anation reactions, reactions without metal
ligand, bond cleavage. Substitution reactions in square
planar complexes, the trans ell'ect, mechanism of the
substitution reaction. Redox reactions, electron transfer
reactions, mechanism of one electron transfer reactions,
outersphere type reactions, cross reactions and
Marcus-Hush theory , inner sphere type reactions
Metal-Ligand Bonding
Limitation of crystal field theory, molecular orbital theory,
octahedral. tetrahedral and square planar complexes,
n-bonding and molecular orbital theory.
Electronic Spectra and Magnetic Properties of
‘ Transition Metal complexes
Spectroscopic ground states, correlation, Orgel and
Tanabe-Sugano diagrams for transition metal complexes
(dl—Id9 states), calculations of Dq, B and fl parameters,
charge transfer spectra, spectroscopic method of
assignment of absolute configuration in optically active
metal chelates and their stereochemical information,
anomalous magnetic moments, magnetic exchange
coupling and spin crossover.

Kanpur University Msc Chemistry Syllabus
kanpuruniversity.org/SYLLABUS/MSC.pdf

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CSJM University
Kanpur University, Kanpur, Uttar Pradesh 208024

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